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WPI Class IV Water Treatment โ€” Formula Sheet

Chief Operator Level ยท Advanced Process Control ยท Plant Management ยท Regulatory Compliance

BC โ€” EOCP Level IVAB โ€” AWWOA Class IVSK โ€” SAHO Class IVMB โ€” MWWA Class IV

Categories

CT Value (Disinfection Credit)

mg/L ยท min
CT = C ร— T
Example

Clโ‚‚ residual = 1.5 mg/L, contact time = 40 min โ†’ CT = 60 mg/Lยทmin

C = disinfectant residual (mg/L) at the outlet; T = theoretical detention time (min). For chlorine at pH 7 and 15ยฐC, CT = 60 achieves 3-log Giardia inactivation.

Effective CT (Baffling Factor)

min
Tโ‚โ‚€ = BF ร— HRT
Example

HRT = 60 min, BF = 0.5 โ†’ Tโ‚โ‚€ = 30 min

BF = baffling factor (0.1โ€“1.0 per regulatory tables). Tโ‚โ‚€ is the time for 10% of tracer to pass through. Use Tโ‚โ‚€ for CT credit calculations.

Log Inactivation (Chick-Watson)

dimensionless
log(Nโ‚€/N) = k ร— C^n ร— T
Example

k = 0.02, C = 1 mg/L, n = 1, T = 30 min โ†’ log inactivation = 0.6

k = rate constant (varies by organism and disinfectant); n = dilution coefficient (typically 1 for chlorine). Used to calculate inactivation credit for regulatory compliance.

Ozone CT for Giardia (3-log)

mg/L ยท min
CT_Oโ‚ƒ = 0.63 mg/Lยทmin (at 15ยฐC, pH 7)
Example

Ozone residual = 0.3 mg/L, Tโ‚โ‚€ = 3 min โ†’ CT = 0.9 > 0.63 โœ“

Ozone is far more effective than chlorine. At 15ยฐC, only 0.63 mg/Lยทmin achieves 3-log Giardia inactivation vs. 60 mg/Lยทmin for chlorine at pH 7.

UV Dose for Giardia (3-log)

mJ/cmยฒ
UV Dose = E ร— t (mJ/cmยฒ)
Example

3-log Giardia requires โ‰ฅ5.8 mJ/cmยฒ; 4-log Cryptosporidium requires โ‰ฅ22 mJ/cmยฒ

UV dose = irradiance (mW/cmยฒ) ร— exposure time (s). UV provides no residual โ€” must be combined with chemical disinfection for distribution system protection.

Disinfection Byproduct (DBP) Formation

ฮผg/L
THM_f = k ร— [NOM] ร— [Clโ‚‚] ร— t^n ร— pH^m ร— T^p
Example

Higher NOM, higher Clโ‚‚ dose, longer contact time, higher pH โ†’ higher THM formation

Simplified empirical relationship. Key levers: reduce NOM before chlorination (enhanced coagulation, GAC), minimize Clโ‚‚ dose, lower pH, reduce contact time before distribution.

โšก Quick Reference โ€” Class IV Key Values

ParameterTypical Value / LimitRegulatory ReferenceNotes
Giardia CT (Clโ‚‚, 15ยฐC, pH 7)60 mg/Lยทmin (3-log)GUDI / Surface Water RegsUse Tโ‚โ‚€ with baffling factor
Ozone CT (Giardia, 3-log)0.63 mg/LยทminGUDIFar more efficient than Clโ‚‚
UV Dose (Giardia, 3-log)5.8 mJ/cmยฒUV Disinfection GuidanceNo residual โ€” combine with Clโ‚‚
UV Dose (Crypto, 4-log)22 mJ/cmยฒUV Disinfection GuidanceCrypto resistant to Clโ‚‚
Filtered turbidity (95th %ile)โ‰ค0.3 NTUO. Reg. 170/03 / Prov. RegsNo single reading >1.0 NTU
THM MAC (RAA)100 ฮผg/LHealth Canada GCDWQRunning annual average
HAA MAC (RAA)80 ฮผg/LHealth Canada GCDWQRunning annual average
Lead MAC10 ฮผg/L (90th %ile)Health Canada GCDWQFirst-draw samples
Fluoride optimal0.7 mg/LHealth CanadaMAC = 1.5 mg/L
Chlorine residual (distribution)โ‰ฅ0.05 mg/L free Clโ‚‚Provincial regulationsMinimum at all points
Notification of adverse resultWithin 24 hoursO. Reg. 170/03To MOH and Director
Baffling factor (poor)0.1CT GuidanceUnbaffled tanks
Baffling factor (excellent)0.7โ€“1.0CT GuidancePlug flow / serpentine
Membrane flux (UF typical)20โ€“80 LMHManufacturer guidanceMonitor for fouling
VFD power savings (20% speed reduction)~49% power reductionAffinity lawsP โˆ Nยณ
๐Ÿ“ Class IV Practice Quiz๐ŸŽฏ Class IV Mock Examโ† Class III Formulas๐ŸŒŠ WPI Hub